Don't worry about synthetic rope and mag chloride! Synth rope is made of UHMWPE (Ultra High Molecular Weight Polyethylene). This is among the most chemically inert substances known to man. In chemical labs, the worst of the worst is stored and decanted in PE. For example, PE is about the only thing you can use for HF (hydroflouric acid) - the stuff eats through normal lab glassware! It will also hold up well against aromatic HCs, such as gasoline and various petroleum solvents.
As was previously noted, mag chloride is stored and dispensed from CDOT trucks in PE tanks. And as was previously noted, those tanks will last far longer than the trucks they are carried on.
FWIW, my synth rope has seen plenty of mag chloride and conventional NaCl and is now in the midst of it's 4th winter, and is doing much better than the GAC it replaced. Synth is way superior to GAC in so many ways!